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Metal Oxide Nanostructures from Simple Metal-oxygen Reaction in Air

Ting YU , Zexaing SHEN

材料科学技术(英)

Metal oxide nanostructures (CuO, Co3O4, ZnO and α-Fe2O3) have been successfully fabricated by a simple and efficient method: heating the appropriate metals in air at low temperatures ranging from 200 to 400℃. The chemical composition, morphology and crystallinity of the nanostructures have been characterized by micro-Raman spectroscopy, X-ray diffraction, scanning electron microscopy and transmission electron microscopy. Two mechanisms: vapor-solid and surface diffusion play dominant roles in the growth of metal oxide nanostructures starting with low melting point metals (Zn and Cu) and high melting point metals (Fe and Co), respectively. With sharp ends and large aspect ratio, the metal oxide nanostructures exhibit impressive field-induced electron emission properties, indicating their potentials as future electron source and displays. The water wettability and anti-wettability properties of iron oxide nanoflakes were also discussed in this work.

关键词: Metal oxide , oxide , nanostructures , field , emiss

RHEOLOGICAL BEHAVIOURS OF CAST STEEL DURING SOLIDIFICATION

LIN Jialiu ZHU Shigen YU Zhenzong Tsinghua University , Beijing , China

金属学报(英文版)

The stress-strain relation for cast low alloy carbon steel at solidification temperature has been examined by the authors' own desingned apparatus for rheological properties measurement.The rheology model,the stress-strain constitutive equation and the rheological parameters therefrom of the cast steel were proposed.Thus the theoretical basis and calcula- ting data for computerized s#nulation on the stress-strain relation and thermal cracking of the cast steel were suggested.

关键词: rheological behaviour , null , null , null , null

FRACTAL GEOMETRY STUDY OF CORRELATION BETWEEN IMPACT TOUGHNESS OF STEEL AND PARAMETERS OF FREE-CUTTING PHASE

JIANG Laizhu CUI Kun Huazhong University of Science and Technology , Wuhan , China

金属学报(英文版)

Studies were made of the calculation of fractal dimension of transverse impact fracture sur- face,and of the correlation between impact toughness of steel and parameters of free-cutting phase by means of the developed fractal geometry model of crack propagation.It is believed that the area fraction,f,of free-cutting phase is negligibly influential to the longitudinal im- pact toughness,as f1 .While the aspect ratio,saying ratio of length to width,of free-cut. ting phase is inversely influential to the transverse impact toughness.This may .be the reason why the transverse impact toughness of free-cutting steel containing more rare earth contrast to sulphur is even higher than the low sulphur containing steel.

关键词: fractal geometry , null , null

FRICTION MARTENSITE AND ITS TEMPERING CHARACTERISTICS

Liu Zhengyi Fu Jian Zhuang Yuzhi South China University of Technology , Guangzhou , China Correspondent:LIU Zhengyi professor , Dept.of Mechanical Engineering No.2 , South China University of Technology , Guangzhou , China

金属学报(英文版)

The nature of“white layer”found in 55SiMnMo steel subjected to friction test has been stu- died using TEM,SEM,X-ray diffraction and EPMA techniques.It is shown that the struc- ture of the“white laver”on the rubbing surface is duplex,consisting of a special martensite and some austenite.This layer may be 25—50 μm thick.It is ultrafine,with grain diametric approximately 30 nm.Its micro-hardness may be as high as Hm 1500 and is capable of cut- ting glass.It has superb corrosion resistance and resists tempering.Its mierostructure and hardness undergo changes only when the steel is tempered above 500℃.

关键词: friction , null , null

Improved Nonlinear Equation Method for Numerical Prediction of Jominy EndQuench Curves

SONG Yuepeng , LIU Guoquan , LIU Shengxin , LIU Jiantao , FENG Chengming

钢铁研究学报(英文版)

Without considering the effects of alloying interaction on the Jominy endquench curves, the prediction results obtained by YU Baihai′s nonlinear equation method for multialloying steels were different from those experimental ones reported in literature. Some alloying elements have marked influence on Jominy endquench curves of steels. An improved mathematical model for simulating the Jominy endquench curves is proposed by introducing a parameter named alloying interactions equivalent (Le). With the improved model, the Jominy endquench curves of steels so obtained agree very well with the experimental ones.

关键词: Jominy endquench curve;nonlinear equation method;alloying interaction parameter;computer simulation

1998 COMPREHENSIVE TABLE OF CONTENTS

中国腐蚀与防护学报

N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat(6)Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac(13)SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch&tllsth Of ThlollY68 Oil ITOll ID H....

关键词:

三维晶粒长大速率方程的大尺度Potts模型Monte Carlo仿真验证

王浩 , 刘国权 , 秦湘阁

金属学报

采用Potts模型Monte Carlo方法对3种现存的三维个体晶粒长大速率拓扑依赖性 方程进行了仿真验证. 结果表明, Rivier速率方程认为晶粒 体积变化率dVf/dt与晶粒面数f成线性关系, 与仿真 结果明显不符, 不适用于描述三维晶粒长大过程的动力 学. 当晶粒面数f≥8时, Yu-Liu速率方程和 MacPherson-Srolovitz速率方程均与仿真结果很好吻合, 表明这两者均可以用来定量描述三维晶粒长大过程的动力学;当 f<8时, 这两个方程均与仿真结果有显著差异.

关键词: 三维晶粒长大 , topology-dependent grain growth rate equation

三维晶粒长大速率方程的大尺度Potts模型Monte Carlo仿真验证

王浩 , 刘国权 , 秦湘阁

金属学报 doi:10.3321/j.issn:0412-1961.2008.01.003

采用Potts模型Monte Carlo方法对3种现存的三维个体晶粒长大速率拓扑依赖性方程进行了仿真验证.结果表明,Rivier速率方程认为晶粒体积变化率dVf/dt与晶粒面数,成线性关系,与仿真结果明显不符,不适用于描述三维晶粒长大过程的动力学.当晶粒面数f≥8时,Yu-Liu速率方程和MacPherson-Srolovitz速率方程均与仿真结果很好吻合,表明这两者均可以用来定量描述三维晶粒长大过程的动力学;当f<8时,这两个方程均与仿真结果有显著差异.

关键词: 三维晶粒长大,拓扑依赖性长大速率方程,Potts模型,Monte Carlo仿真

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